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pKa and pKb Calculator – Convert Ka, Kb, pKa, and pKb

Convert between Ka, Kb, pKa, and pKb values effortlessly with our pKa/pKb calculator. Use the relationship pKa + pKb = 14 to find acid and base dissociation constants. Essential for acid-base chemistry and biochemistry.

Understanding pKa and pKb

pKa and pKb are logarithmic measures of acid and base strength. Lower pKa values indicate stronger acids. Lower pKb values indicate stronger bases.

Formulas

pKa = -log₁₀(Ka)
pKb = -log₁₀(Kb)
Ka = 10⁻ᵖᴷᵃ
Kb = 10⁻ᵖᴷᵇ
pKa + pKb = 14 (at 25°C)

Acid Strength Guide

pKa RangeAcid StrengthExample
< 0Very StrongHCl (-7)
0-3StrongH₃PO₄ (2.1)
3-7ModerateAcetic acid (4.76)
7-14WeakNH₄⁺ (9.25)
> 14Very WeakH₂O (15.7)

Example: Acetic Acid

Ka = 1.8 × 10⁻⁵

pKa = -log₁₀(1.8 × 10⁻⁵) = 4.74

pKb = 14 - 4.74 = 9.26

pKa and Ka Relationship

Enter values and calculate to see the graph

Common pKa Values
AcidFormulapKaKa
HydrochloricHCl-710⁷
AceticCH₃COOH4.761.8 × 10⁻⁵
CarbonicH₂CO₃6.354.5 × 10⁻⁷
AmmoniumNH₄⁺9.255.6 × 10⁻¹⁰
WaterH₂O15.72 × 10⁻¹⁶
How to Use the pKa pKb Calculator
1

Choose your conversion type

Select from Ka to pKa, pKa to Ka, Kb to pKb, pKb to Kb, or pKa-pKb interconversion.

2

Enter your value

Input the dissociation constant or p-value. Use scientific notation for Ka/Kb (e.g., 1.8e-5).

3

Get instant results

View the converted value plus a graph showing the relationship between parameters.

Benefits for Chemistry Students

Six conversion modes

Handle any Ka, Kb, pKa, or pKb conversion in one tool.

Visual relationship graphs

See how Ka and pKa relate across different values.

Acid strength reference

Built-in table classifies acids from very strong to very weak.

Common pKa values

Quick lookup table for HCl, acetic acid, carbonic acid, and more.

Scientific notation support

Enter values like 1.8e-5 directly without manual conversion.

Frequently Asked Questions

What is the formula for pKa?

pKa = -log10(Ka). For acetic acid with Ka = 1.8 × 10^-5, pKa = -log10(1.8 × 10^-5) = 4.74.

How do you convert pKa to pKb?

Use pKa + pKb = 14 at 25°C. If pKa = 4.76, then pKb = 14 - 4.76 = 9.24.

What does a low pKa value mean?

Low pKa indicates a strong acid that dissociates completely. pKa less than 0 means very strong acid like HCl.

What is Ka in chemistry?

Ka is the acid dissociation constant. It measures how much an acid dissociates in water. Higher Ka means stronger acid.

Why is pKa + pKb = 14?

This comes from Kw = [H+][OH-] = 10^-14 at 25°C. Taking -log of both sides gives pKa + pKb = 14.

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